人教版高中化学教科书“研究与实践”栏目分析与实施策略*

对人教版高中化学教科书新设计的“研究与实践”栏目的主题内容、功能价值进行分析,就如何充分发挥该栏目的教学功能和价值,发展学生的化学学科核心素养,提出了创设教学情境线索、开发为研究性学习课题、开发为校本选修课程、开发为STEM课程等实施策略。     

Concise Construction of the ACDE Ring System of Calyciphylline A Type Alkaloids by a [5+2] Cycloaddition

A concise route for construction of the ACDE ring skeleton in calyciphylline A type alkaloids was developed using an intramolecular [5+2] cycloaddition reaction of an oxidopyrylium species bearing a tetrasubstituted olefin. Key to the success of this reaction was the combination of acid and base, which accelerated the construction of this skeleton containing a spiro ring and vicinal quaternary carbon centers. The resultant tricyclic ADE ring compound was converted to an ACDE ring model through C−H oxidation and an aza-Wittig reaction.     

Selective Excitation of Band Extrema in Valley Photonic Crystals

Flexible control of building blocks of photonic crystals enables achieving desirable band structures. Exploration of photonic band extrema has brought many fantastic features to design artificial optical materials, such as Brillouin‐zone‐corner extrema for valley photonic materials and zone‐center extremum for zero‐index metamaterials. However, two such kinds of extrema are always found independently in different photonic crystals. In this work, a kind of valley photonic crystals possessing both zone‐center and zone‐corner band extrema almost at the same frequency is proposed. Inspired by antennas theory, a three‐antenna array (TAA) source is devoted to individually manipulate each extremum. The correlation coefficient is given to determine the coupling efficiency between the TAA source and extrema eigenmodes. By using a source with a high correlation coefficient, these extrema bulk states are selectively excited consistent with their eigenfields. Furthermore, three control cases are shown that multiple extrema points are simultaneously excited, in order to confirm the validity of the correlation coefficient. Finally, a potential application of a beam‐steering device is proposed through selective excitation of ternary extrema. This work develops binary valley states into ternary mix states, rendering more degrees of freedom for on‐chip optical information transport, particularly for beam steering and mode division multiplexing.     

Optical and static dielectric study of a terminally fluorinated liquid crystalline compound

Optical and static dielectric studies on a terminally fluorinated liquid crystalline compound have been carried out. Measurements of temperature variation of refractive indices of the compound are done by using thin prism method. A four-parameter model is validated by fitting the experimentally measured values of refractive indices, birefringence and average refractive indices of the compound with the theoretical ones. Refractive index and density data are utilized for determination of orientational order parameter. The temperature variation of dielectric permittivities of the compound are measured by a LCR meter.     

多层网络级联失效的预防和恢复策略概述

现实生活中,与国计民生密切相关的基础设施网络大多不是独立存在的,而是彼此之间相互联系或依赖的,于是用于研究这些系统的多层网络模型随之产生.多层网络中的节点在失效或者遭受攻击后会因"层内"和"层间"的相互作用而产生级联效应,从而使得失效能够在网络层内和层间反复传播并使得失效规模逐步放大.因此,多层网络比单个网络更加脆弱.多层网络级联失效产生的影响和损失往往是非常巨大的,所以对多层网络级联失效的预防和恢复的研究具有重大意义.就多层网络级联失效的预防而言,主要包含故障检测,保护重要节点,改变网络耦合机制和节点备份等策略.就多层网络发生级联失效后的恢复策略而言,主要包含共同边界节点恢复、空闲连边恢复、加边恢复、重要节点优先恢复、更改拓扑结构、局域攻击修复、自适应边修复等策略.     

相对性区域创新指数与经济周期挖掘

提出了一类新的相对性区域创新指数,并采用世界专利申请数据对其进行了具体计算.基于区域创新同经济发展水平之间的超线性关系,该指数消除了经济发展水平对创新能力的影响,可以实现对不同发展水平的经济体之间进行有效的创新能力横纵对比.该创新指数尽管极其简单,却揭示出一系列迥异于传统认知的现象,例如中国大陆地区的技术创新能力在1980年代就已经位居世界前列.采用该指数,不但可以在较高水平上解释世界各国的经济增长,还发现它同经济增长率之间的相关性存在一个20年的经济周期.这些结果显示,该指数作为一个单一性指标,以极小的数据依赖就实现了较高程度的解释性,不但重新定位了世界各经济体的创新能力,对深入理解创新同经济发展之间的关系提供了新的角度,而且暗示着这类相对性经济指标的发展潜力与应用空间.     

Controllable tomography phase microscopy

Tomography phase microscopy (TPM) is a new microscopic method that can quantitatively yield the volumetric 3D distribution of a sample׳s refractive index (RI), which is significant for cell biology research. In this paper, a controllable TPM system is introduced. In this system a circulatory phase-shifting method and piezoelectric ceramic are used which enable the TPM system to record the 3D RI distribution at a more controllable speed, from 1 to 40 fps, than in the other TPM systems reported. The resolution of the RI distribution obtained by this controllable TPM is much better than that in images recorded by phase contrast microscopy and interference tomography microscopy. The realization of controllable TPM not only allows for the application of TPM to the measurement of kinds of RI sample, but also contributes to academic and technological support for the practical use of TPM.